data_1527305
_publ_section_title
;
 Crystal and molecular structures of tungsten(VI) sulfide tetrachloride
 and tungsten(VI) sulfide tetrabromide
;
_journal_name_full
;
Journal of the Chemical Society A: Inorganic, Physical, Theoretical (1966-1971)
;
_journal_page_first              2815
_journal_page_last               2818
_journal_volume                  1970
_journal_year                    1970
_chemical_formula_sum            'Cl4 S W'
_chemical_name_systematic        'W S Cl4'
_space_group_IT_number           2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                85.96
_cell_angle_beta                 104.3
_cell_angle_gamma                111.24
_cell_formula_units_Z            2
_cell_length_a                   8.278
_cell_length_b                   6.092
_cell_length_c                   6.923
_cell_volume                     315.256
_citation_journal_id_ASTM        JCSIAP
_cod_data_source_file            Drew_JCSIAP_1970_1850.cif
_cod_data_source_block           Cl4S1W1
_cod_original_cell_volume        315.2558
_cod_chemical_formula_sum_orig   'Cl4 S1 W1'
_cod_database_code               1527305
loop_
_symmetry_equiv_pos_as_xyz
x,y,z
-x,-y,-z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
W1 W+6 -0.2173 0.1353 0.2467 1 0.0
Cl3 Cl-1 -0.4701 0.0807 0.2646 1 0.0
Cl1 Cl-1 0.0823 0.1162 0.3475 1 0.0
S1 S-2 -0.2933 0.3079 -0.0315 1 0.0
Cl2 Cl-1 -0.2865 0.4502 0.4478 1 0.0
Cl4 Cl-1 -0.1037 -0.2493 0.1564 1 0.0
