data_9012328
_publ_section_title
;
 Uber Wismutoxide. VI. Uber ein Wismut(III)-oxid mit hoherem sauerstoffgehalt
 (beta-modifikation)
 Locality: synthetic
;
_journal_name_full
'Zeitschrift fur Anorganische und Allgemeine Chemie'
_journal_page_first              44
_journal_page_last               68
_journal_paper_doi               10.1002/zaac.19643280106
_journal_volume                  328
_journal_year                    1964
_chemical_formula_sum            'Bi2 O3'
_chemical_name_mineral           Sphaerobismoite
_symmetry_space_group_name_H-M   'C -4 2 b'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_length_a                   10.95
_cell_length_b                   10.95
_cell_length_c                   5.63
_cell_volume                     675.051
_exptl_crystal_density_diffrn    9.170
_cod_database_code               9012328
loop_
_symmetry_equiv_pos_as_xyz
x,y,z
1/2+x,1/2+y,z
1/2+y,x,z
+y,1/2+x,z
1/2-x,y,-z
-x,1/2+y,-z
1/2-y,-x,z
-y,1/2-x,z
1/2+x,-y,-z
+x,1/2-y,-z
y,-x,-z
1/2+y,1/2-x,-z
-x,-y,z
1/2-x,1/2-y,z
-y,x,-z
1/2-y,1/2+x,-z
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
Bi 0.13500 0.11500 0.25000 0.05699
O1 0.02000 0.25000 0.00000 0.05699
O2 0.02000 0.25000 0.50000 0.05699
O3 0.25000 0.25000 0.00000 0.05699
O4 0.00000 0.00000 0.50000 0.05699
